When he wasn't composing complete Original scores for this 1950's Radio Series, Jerry Goldsmith acted as Music Supervisor. Many episodes usually included some music by the composer.
Here is some of Goldsmith's spanish flavored original music from the episode "The Guitar" which is performed by Laurindo Almeida, José Barroso and Nicholas Dan. Listen for Goldsmith's and the Guitarist's names in the announcer end credits. Enjoy!
Don't remember it being on the "Early Years" CD. I found the CBS RADIO Romance shows at the link below. You can listen to tons of them. Several with Goldsmith scores and many Music Supervised by the maestro.